Article ID Journal Published Year Pages File Type
1306829 Inorganica Chimica Acta 2010 6 Pages PDF
Abstract
The mixed tetrel Zintl phase Ba8Si6Sn consists of two different blocks of the composition Ba2Sn and Ba6(Si36-)2, respectively. The Si36--units are isolated three membered rings. The triangles are best described as pseudo-sulfur units with two single bonds per atom according to the Zintl-Klemm concept. The tin atoms are isolated and have a formal charge of 4−.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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