| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306830 | Inorganica Chimica Acta | 2010 | 7 Pages |
In this article we propose a model of spin-vibronic relaxation in K6[VIV15As6O42(H2O)]·8H2O, the so called V15 cluster exhibiting the unique layered structure. The work is motivated by the recent observation of the Rabi oscillation [1] in this system and aimed to elucidate the nature of the relaxation processes. The model assumes that the spin-phonon coupling arises as a result of modulation of the isotropic and antisymmetric (Dzyaloshinsky–Moriya) exchange interactions in the central triangular layer of vanadium ions by the acoustic lattice vibrations. Within the pseudo-angular momentum representation the selection rules for the direct (one-phonon) transitions between Zeeman levels are derived and a special role of the antisymmetric exchange is underlined. The relaxation times related to one-phonon transitions in different ranges of the field are estimated within the Debye model for the lattice vibrations.
Graphical abstractA model of spin-vibronic relaxation in V15 cluster, K6[VIV15As6O42(H2O)]·8H2O, is proposed. The spin-phonon coupling arises as a result of modulation of the isotropic and Dzyaloshinsky–Moriya exchange interactions in the central triangular layer of VIV ions by acoustic lattice vibrations. The selection rules for the one-phonon transitions are derived and the relaxation times in different ranges of the field are estimated.Figure optionsDownload full-size imageDownload as PowerPoint slide
