Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1306878 | Inorganica Chimica Acta | 2010 | 5 Pages |
Abstract
Reaction of NO with [(Me2bpb)Fe(py)2]+ in acetonitrile affords both N- and O-bound NO2-isomers [(Me2bpb)Fe(NO)(NO2)] and [(Me2bpb)Fe(NO)(ONO)]. Formation of both isomers is reminiscent of iron-porphyrin chemistry and indicates small difference in binding energy of the NO2 ligand via N- and O-center to the {Fe-NO}6 moiety.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Michael J. Rose, Apurba K. Patra, Marilyn M. Olmstead, Pradip K. Mascharak,