Article ID Journal Published Year Pages File Type
1307022 Inorganica Chimica Acta 2009 6 Pages PDF
Abstract

A 1D coordination polymer, {[Cu3(C7H2NO5)2(H2O)7]·2(H2O)}n (1), has been synthesized and characterized by X-ray single-crystal diffraction. The crystal structure of 1 features that distorted square–pyramidal coordination polyhedra composed of Cu atoms and chelidamic acid ligands are interlinked into a 1D polymer, further linked by hydrogen bonds into a 3D network. The optical properties were investigated in terms of diffuse reflectance and fluorescent spectra, which exhibit strong luminescence. The electronic band structure along with the density of states (DOSs) calculated by the DFT method indicate that compound 1 pose an energy band gap of 1.89 eV and that the origin of the emission band may be mainly ascribed to metal-to-ligand charge transfer (MLCT) where the electrons are transferred from the Cu-3d to O-2p and C-2p states.

Graphical abstractA 1D coordination polymer, {[Cu3(C7H2NO5)2(H2O)7]·2(H2O)}n (1), has been synthesized and characterized by X-ray single-crystal diffraction. The crystal structure of 1 features that distorted square–pyramidal coordination polyhedra composed of Cu atoms and chelidamic acid ligands are interlinked into a 1D polymer, further linked by hydrogen bonds into a 3D network.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
, , , , , , , ,