Article ID Journal Published Year Pages File Type
1307031 Inorganica Chimica Acta 2009 6 Pages PDF
Abstract
Two isomeric O2S2 macrocycles L1 and L2 were synthesised and their coordination chemistry towards Pd(II) was investigated. Two-step approaches via reactions of 1:1 complexes, [cis-Cl2LPd] (1a: L = L1, 1b: L = L2), with different macrocycles led to the isolation of the following bis(O2S2 macrocycle) Pd(II) complexes: [Pd(L1)2](ClO4)2 (2a) and a mixture of [Pd(L1)2](ClO4)2 (2a) + [Pd(L2)2](ClO4)2(2b).
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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