| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1307051 | Inorganica Chimica Acta | 2009 | 5 Pages |
Abstract
Alkylation reactions of [Pt2(μ-E)2(PPh3)4] with cis-1,4-dichlorobut-2-ene (cis-ClCH2CHCHCH2Cl) gives the complexes [Pt2(μ-ECH2CHCHCH2E)(PPh3)4]2+, which undergo a facile fragmentation reaction in ESI mass spectrometry, via a retro-Diels-Alder reaction and loss of 1,3-butadiene, giving the dichalcogenide species [Pt2(μ-E2)(PPh3)4]2+.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Dithiolate and diselenolate complexes [Pt2(μ-ECH2CHCHCH2E)(PPh3)4]2+ (E = S, Se): Synthesis, characterisation and mass spectrometric formation of the dichalcogenide species [Pt2(μ-E2)(PPh3)4]2+](/preview/png/1307051.png "First Page Preview: Dithiolate and diselenolate complexes [Pt2(μ-ECH2CHCHCH2E)(PPh3)4]2+ (E = S, Se): Synthesis, characterisation and mass spectrometric formation of the dichalcogenide species [Pt2(μ-E2)(PPh3)4]2+")
Authors
Sarah M. Devoy, William Henderson, Brian K. Nicholson, T.S. Andy Hor,