Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307053 | Inorganica Chimica Acta | 2009 | 5 Pages |
Abstract
New bis(macrocyclic) dinickel(II) complexes with bis(Me2[14]-4,7-dien-6-ylidene), 2a and 2b, were synthesized by oxidation of a dinickel(II) complex with an unsaturated bis(macrocyclic) ligand containing four CN bonds, bis(Me2[14]-4,7-dien-6-yl). Complex 2a was found to undergo intramolecular cyclization between the methyl group of one macrocycle and the carbon atom of the CN group of the other macrocycle to produce a bis(macrocyclic) dinickel(II) complex bridged by a five-membered ring (3).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Katsura Mochizuki, Tomoko Sugita, Fumi Yamada, Nahoko Mochizuki, Kiyoharu Hayano, Yasunobu Ohgami,