| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1307058 | Inorganica Chimica Acta | 2009 | 5 Pages |
Three novel complexes [Mn(atza)2(H2O)4] (1), [Mn(nptza)2(CH3OH)4] (2), and [Mn(a4-ptz)2(H2O)2]n · 2nH2O] (3) [atza = 5-aminotetrazole-1-acetato, nptza = 5-[(4-nitryl)phenyl] tetrazole-1-acetato, a4-ptz = 5-[N-acetato(4-pyridyl)] tetrazole] containing carboxylate–tetrazolate ligands have been synthesized and characterized by element analysis. X-ray crystallography shows that complexes 1 and 2 both contain mononuclear structure. The complex 3 is a 1D polymeric chain structure. Compounds 1–3 are self-assembled to form supramolecular structures through hydrogen bonds interactions.
Graphical abstractThree novel complexes [Mn(atza)2(H2O)4] (1), [Mn(nptza)2(CH3OH)4] (2), and [Mn(a4-ptz)2(H2O)2]n · 2nH2O] (3) containing carboxylate–tetrazolate ligands have been synthesized and characterized. Compounds 1–3 are self-assembled to form supramolecular structures through hydrogen bonds interactions.Figure optionsDownload full-size imageDownload as PowerPoint slide
