Article ID Journal Published Year Pages File Type
1307062 Inorganica Chimica Acta 2009 7 Pages PDF
Abstract
The reactions of heme, [OEPFeCl] where OEP is the dianion of octaethylporphyrin, with phenylcyanamide (pcyd) ligands have been studied. Four new porphyrin complexes, [OEPFe(L)] (L = pcyd (2), 2-Clpcyd (3), 2-Mepcyd (4), 2,4-Me2pcyd (5)), have been isolated and characterized by spectroscopic methods. 1H NMR spectroscopy reveals that the species [OEPFe(L)] are paramagnetic and iron is five-coordinate. The structure of [OEPFe(pcyd)] (2) has been determined by X-ray diffraction analysis.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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