Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307062 | Inorganica Chimica Acta | 2009 | 7 Pages |
Abstract
The reactions of heme, [OEPFeCl] where OEP is the dianion of octaethylporphyrin, with phenylcyanamide (pcyd) ligands have been studied. Four new porphyrin complexes, [OEPFe(L)] (LÂ =Â pcyd (2), 2-Clpcyd (3), 2-Mepcyd (4), 2,4-Me2pcyd (5)), have been isolated and characterized by spectroscopic methods. 1H NMR spectroscopy reveals that the species [OEPFe(L)] are paramagnetic and iron is five-coordinate. The structure of [OEPFe(pcyd)] (2) has been determined by X-ray diffraction analysis.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mozhgan Khorasani-Motlagh, Nasser Safari, Meissam Noroozifar, Hashem Shahroosvand, Brian O. Patrick,