Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307107 | Inorganica Chimica Acta | 2013 | 7 Pages |
Abstract
⺠Viable Cp2Fe2(PF)(CO)4 structures have a PF group bridging two CpFe(CO)2 moieties. ⺠The low energy Cp2Fe2(PF)(CO)3 structures have one PF bridge and one CO bridge. ⺠The lowest energy Cp2Fe2(PF)(CO)2 structure is a triply bridged triplet spin state. ⺠Higher spin states are preferred over Fe-Fe multiple bonds in Cp2Fe2(PF)(CO)n (n = 1, 0). ⺠Cp2Fe2(PF)(CO)n (n = 1, 0) structures are found with separate P and F ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Liqing Zhou, Guoliang Li, Qian-Shu Li, Yaoming Xie, R. Bruce King,