Article ID Journal Published Year Pages File Type
1307193 Inorganica Chimica Acta 2013 5 Pages PDF
Abstract
► Fe4 cluster-bonded phosphonium and phosphine oxide are prepared. ► Reaction of Cp3Fe4(CO)4(C5H4PPh2) with Me+ produces [Cp3Fe4(CO)4(C5H4PPh2Me)]+. ► Treatment of Cp3Fe4(CO)4(C5H4PPh2) with H2O2 leads to Cp3Fe4(CO)4(C5H4PPh2(O)). ► The redox potentials of the product are shifted anodically.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Synthesis and characterization of phosphonium and phosphine oxide linked to a tetrairon cluster
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