Article ID Journal Published Year Pages File Type
1307229 Inorganica Chimica Acta 2008 11 Pages PDF
Abstract
The Co2(CO)6(dppm) and Co2(CO)5(CHCO2Et)(dppm) complexes have been synthesized and characterized by liquid- and solid-state NMR spectroscopy and X-ray crystallography. The kinetics of the 13CO incorporation has been measured by means of IR spectroscopy. Theoretical calculations have been taken in order to explore the mechanisms of CO dissociation reactions and the intramolecular rearrangements.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Structure of Co2(CO)6(dppm) and Co2(CO)5(CHCO2Et)(dppm) (dppm = Ph2PCH2PPh2) and exchange reaction with 13CO: An experimental and computational study
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