Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307267 | Inorganica Chimica Acta | 2008 | 5 Pages |
Abstract
From the low temperature absorption spectra of Dy(btmsa)3, a truncated crystal field (CF) splitting pattern was derived, and simulated by fitting the free parameters of a phenomenological Hamiltonian. The title compound shows strong spectrochemical, nephelauxetic and relativistic nephelauxetic effects. The experimentally based non-relativistic molecular orbital scheme (in the f range) of Dy(btmsa)3 is set up.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
S. Jank, H. Reddmann, H.-D. Amberger,