Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307359 | Inorganica Chimica Acta | 2008 | 8 Pages |
Abstract
Photolysis of FeL3, CoL3, NiL2, CuL2 and ZnL2, where L = S2CNEt2, in PVC matrices at ca. 90 K results in photooxidation of the metal complexes through irreversible metal to solvent charge transfer. DFT quantum mechanical studies of the S2CNMe2 anion and the Ni, Cu and Zn derivatives were carried out, providing a more nuanced understanding of the bonding of the dithiocarbamate ligand than suggested by classical resonance arguments.
Graphical abstractPhotolysis of FeL3, CoL3, NiL2, CuL2 and ZnL2, where L = S2CNEt2, in PVC matrices at ca. 90 K results in photooxidation of the metal complexes through irreversible metal to solvent charge transfer.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Thomas E. Bitterwolf,