Article ID Journal Published Year Pages File Type
1307384 Inorganica Chimica Acta 2008 5 Pages PDF
Abstract

A novel trinuclear nickel(II) complex, [Ni3(L)2(H2O)2](ClO4)2, where L is a bridging unsymmetrical tetradentate ligand, involving o-phenylenediamine, diacetyl monoxime and acetylacetone (H2L = 4-[2-(3-hydroxy-1-methyl-but-2-enylideneamino)-phenylimino]-pentan-2-one oxime) has been synthesized and characterized structurally. In the complex, an octahedral Ni(II) centre is held in the middle by two square planar units with the aid of oxime and ketonic bridges.

Graphical abstractA novel trinuclear nickel(II) complex, [Ni3(L)2(H2O)2](ClO4)2 (H2L = 4-[2-(3-hydroxy-1-methyl-but-2-enylideneamino)-phenylimino]-pentan-2-one oxime) has been synthesized and characterized structurally. In the complex, an octahedral Ni(II) centre is held in the middle by two square planar units with the aid of oxime and ketonic bridges.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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