Synthesis, characterizations, and crystal structures of triorganotin(IV) derivatives with areneseleninic acids

Six new triorganotin(IV) complexes, [R3Sn(O2SeC6H4Cl)]n (R = Me 1; Ph 2), [R3Sn(O2SeC6H4Me)]n (R = Me 3; Ph 4), [R3Sn(O2SeC6H4Bu)]n (R = Me 5; Ph 6) have been synthesized by the reaction of 4-chlorobenzeneseleninic acid, p-Tolueneseleninic acid, and 4-tert-butylbenzeneseleninic acid with triorganotin(IV) chloride in the presence of sodium ethoxide. All of the complexes were characterized by elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectroscopy, and X-ray crystallography. Crystal structures show that all of the complexes exhibit 1D infinite chain structures which are generated by the bidentate oxygen atoms and the five-coordinated tin centers.

Graphical abstractSix new triorganotin(IV) derivatives with areneseleninic acids, [R3Sn(O2SeC6H4Cl)]n (R = Me 1; Ph 2), [R3Sn(O2SeC6H4Me)]n (R = Me 3; Ph 4), [R3Sn(O2SeC6H4Bu)]n (R = Me 5; Ph 6), have been synthesized and characterized. Crystal structures show that all of the complexes exhibit 1D infinite chain structures which are generated by the bidentate bridging seleninic groups.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Six new triorganotin(IV) complexes with areneseleninic acids were synthesized. ► All of the complexes exhibit 1D infinite chain structures. ► The ligands are areneseleninic acids.