Article ID Journal Published Year Pages File Type
1307538 Inorganica Chimica Acta 2011 5 Pages PDF
Abstract
► New gold-rhenium clusters 4 and 5 were synthesized by the reaction of Au(PPh3)(C4Fc) with Re2(CO)8(NCMe)2. ► Formation of cluster 5 is accompanied by the cleavage of the С-С bond of the parent butadiynyl ligand. ► X-ray structure of gold-rhenium clusters 4 and 5. ► Cluster 5 contains two moieties, dicarbide μ4-C2 and alkynyl μ3-C2Fc.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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