Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307582 | Inorganica Chimica Acta | 2008 | 4 Pages |
Abstract
The mercury(I) complexes [Hg2(phen)4](OTf)2 and [Hg2(phen)2](OTf)2 (phen = 1,10-phenanthroline) were prepared and characterized by single crystal X-ray diffraction. The structure of [Hg2(phen)4](OTf)2 exhibits an Hg2N8 kernel, which involves the highest number of N-donor atoms coordinated to Hg22+ reported so far. The Hg–N distances of [Hg2(phen)4](OTf)2 cover a range of 238.5–266.6 pm. Supramolecular structures were built in both complexes via π–π stacking of the phenanthroline ligands.
Graphical abstractThe mercury(I) complex [Hg2(phen)4](OTf)2 exhibits a Hg2N8 kernel, which involves the highest number of N-donor atoms coordinated to Hg22+ reported so far.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Richard Malleier, Walter Schuh, Holger Kopacka, Klaus Wurst, Paul Peringer,