| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1307584 | Inorganica Chimica Acta | 2008 | 11 Pages |
Abstract
The oxidative addition kinetics of CH3I to [Rh((C4H3S)COCHCOCF3)(CO)(PPh3)], studied by UV/vis, IR and NMR techniques, consists of two reaction steps involving two isomers each of a RhIII-acyl and two different RhIII-alkyl species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![A kinetic study of the oxidative addition of methyl iodide to [Rh((C4H3S)COCHCOCF3)(CO)(PPh3)] utilizing UV/vis and IR spectrophotometry and 1H, 19F and 31P NMR spectroscopy. Synthesis of [Rh((C4H3S)COCHCOCF3)(CO)(PPh3)(CH3)(I)]](/preview/png/1307584.png "First Page Preview: A kinetic study of the oxidative addition of methyl iodide to [Rh((C4H3S)COCHCOCF3)(CO)(PPh3)] utilizing UV/vis and IR spectrophotometry and 1H, 19F and 31P NMR spectroscopy. Synthesis of [Rh((C4H3S)COCHCOCF3)(CO)(PPh3)(CH3)(I)]")
Authors
Marrigje M. Conradie, Jeanet Conradie,