Ring folding in cyclopentadienyl diazabutadiene complexes of group 4 and 5 transition metals

The syntheses of CpM(i-PrDAB)2 (M = Nb, Ta; Cp = (C5H5); i-PrDAB = bis-isopropyl-1,4-diazabuta-1,3-diene) are reported. Both show fluxional NMR spectra indicating that the two DAB rings differ. The X-ray crystal structure of CpNb(i-PrDAB)2 shows one ring to be more folded than the other. Density functional calculations have been used to investigate the degree of folding of the chelate ring in the compounds Cp2M(R-DAB), (M = Ti, Zr, Hf, Nb, Ta; R = H, i-Pr; DAB = 1,4-diazabuta-1,3-diene) and CpM(R-DAB)2 (M = Nb and Ta). For Cp2M(R-DAB) the group 4 compounds all have folded rings whereas the Nb and Ta compounds have planar rings. In all compounds the rings are reduced and the folding is driven by the electron number requirements of the metal centre.

Graphical abstractDiazabutadiene rings when folded on coordination to a metal are acting as LX2 ligands with donation from the filled π3 orbital to the metal via the N atoms.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► The new compounds CpM(i-PrDAB)2 (M = Nb, Ta) have been synthesized. ► Folded MDAB rings are investigated in these and Cp2MDAB complexes by DFT. ► The origin of folding is interaction of the metal with the pπ electrons on the Ns. ► The C–C backbone of the DAB ligand is not coordinated to the metal.