Article ID Journal Published Year Pages File Type
1307671 Inorganica Chimica Acta 2011 6 Pages PDF
Abstract
► Anions derived from trimethylboron have weaker B-C bonds than does trimethylboron. ► The theory of atoms in molecules (AIM) provides a consistent picture of bonding at trigonal centers. ► Carbocatiions and alkylboranes both have bond orders close to 1.5, based on AIM calculations. ► In contrast to silicon analogs, neutral alkylboranes are stabilized by hyperconjugation.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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