Article ID Journal Published Year Pages File Type
1307723 Inorganica Chimica Acta 2007 5 Pages PDF
Abstract
The reaction of [Cp2′Nb(Te2)H](1) (Cp′ = t-BuC5H4) with CH3Li in THF simultaneously gave diamagnetic [Cp2′NbH2(TeCH3)](2) and paramagnetic [Cp2′Nb(TeCH3)2](4). The subsequent reaction of 4 with [Co2(CO)8] gave [Cp2′Nb(μ-TeCH3)2Co(CO)2](5). The compounds have been characterized by IR, ESR, MS and variable temperature 1H NMR spectroscopy.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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