Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307739 | Inorganica Chimica Acta | 2007 | 6 Pages |
Abstract
Reaction of C6H5NCS with MoS42- led to the formation of a dinuclear complex of molybdenum(V) with two dithiocarboimidate ligands, (NEt4)2[Mo2(S)2(μ-S)2(η2-S2CN(C6H5))2] · 0.5CO(CH3)2. The crystallization of 1 is systematically accompanied by the formation of 4-phenyl-3,5-diphenylimino[1,2,4]-dithiazolidine [(C6H5)3N3C2S2] (2). The two compounds have been structurally characterized by XRD and a reaction scheme is proposed.
Graphical abstractSyntheses in one-step and characterizations of (NEt4)2[Mo2(S)2(μ-S)2(η2-S2CN(C6H5))2] · 0.5CO(CH3)2 (1) and of 4-phenyl-3,5-diphenylimino[1,2,4]-dithiazolidine[(C6H5)3N3C2S2] (2) are presented.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Alain Mallard, Jérôme Marrot, Corine Simonnet-Jégat, Francis Sécheresse,