N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric 4f and 3d–4f heterodinuclear complexes: Syntheses, crystal structures and magnetic properties

Three novel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane dimeric lanthanide complexes, namely, [{H2L}Sm(NO3)3]2·H2O (1), [{H2L}Gd(NO3)3]4·CH3OH (2), [{H2L}Lu(NO3)3]4·H2O (3) (H2L = N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) and three new N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane 3d-Gd heterodinuclear complexes, namely, [{LCo}(CH3COO)(CH3COOH)Gd(NO3)2] (4), [{LNi(MeOH)2}Gd(NO3)3]·2MeOH (5) and [{(L)Zn(HNO3)}Gd(NO3)3]·NO3·H3O·MeOH (6) have been synthesized and isolated. X-ray crystallographical analysis reveals that complexes 1–3 are isomorphic with unique dimeric topology. Complexes 4–6 are of discrete 3d–4f dinuclear cores. Magnetic properties of complexes 2 and 4–6 are systematically investigated. Complexes 4 and 5 are ferromagnetic, while 2 and 6 are antiferromagnetic.

Graphical abstractNovel N,N′-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane lanthanide complex with unique dimeric topology and antiferromagnetic coupling between the Gd(III) ions.Figure optionsDownload full-size imageDownload as PowerPoint slide