Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1307990 | Inorganica Chimica Acta | 2010 | 11 Pages |
Abstract
Deprotonation of the coordinated macrocyclic ligand at the nitrogen atom substantially increases reactivity of the chromium(III) complex. Specific outer sphere interactions between the cationic reactant and a counter ion of the supporting electrolyte (Scheme) determine the form of the rate law.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Anna Katafias, Janusz ChatÅas, Olga Impert, PrzemysÅaw Kita, Edyta Madej, Adrian Topolski, Grzegorz Wrzeszcz, Jette Eriksen, Ole Mønsted, Andrew Mills,