| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308133 | Inorganica Chimica Acta | 2014 | 6 Pages |
Abstract
Heterometallic yellow compound Ba3[Fe(C2O4)3]2(H2O)12 (1) could be transformed to heterometallic red compound Ba4.5[Fe4O(OH)3(C2O4)8]-(H2O)19 (2) in solution. Ba2+ and Fe3+ formed three-dimensional network thorough oxalate anion and H2O molecules. 1 is a paramagnet and a strong antiferromagnetic interaction in OH/O bridged tetranuclear anion [Fe4O(OH)3(C2O4)89â] as ground state of SÂ =Â 0 exists in 2.57
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, crystal structures and characterization of two heterometallic compounds: Ba3[Fe(C2O4)3]2(H2O)12 and Ba4.5[Fe4O(OH)3(C2O4)8](H2O)19](/preview/png/1308133.png "First Page Preview: Synthesis, crystal structures and characterization of two heterometallic compounds: Ba3[Fe(C2O4)3]2(H2O)12 and Ba4.5[Fe4O(OH)3(C2O4)8](H2O)19")
Authors
Bin Zhang, Yan Zhang, Guangcai Chang, Zengqiang Gao, Dongwei Wang, Daoben Zhu,