| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308135 | Inorganica Chimica Acta | 2014 | 5 Pages |
•A novel secondary carbinol form of di-3-pyridylmethanone was observed.•The metal complexes of the secondary carbinol form were characterized.•New one-pot insitu method to synthesize complex of DPK family was reported.
Cadmium(II) trifluoroacetate and silver(I) pentafluoropropionate complexes with the secondary carbinol form of di-3-pyridylmethanone were successfully produced through one-pot insitu method in the presence of aluminum powder and potassium fluoride under mixed-solvent thermal condition. Such one-pot insitu method is the first example to synthesize a metal complex with a secondary carbinol form of di-pyridyl ketone family.
Graphical abstractTwo new metal complexes with a novel secondary carbinol form of di-3-pyridylmethanone were successfully obtained through one-pot insitu method under solvent-thermal condition.Figure optionsDownload full-size imageDownload as PowerPoint slide
