| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308214 | Inorganica Chimica Acta | 2016 | 5 Pages |
•2D trans-cyano-bridged MnIII–FeIII complex was synthesized.•Crystal structure of complex 1 has been described.•Photoluminescence properties and magnetic behavior of complex 1 have been studied.
A trinuclear cyanide-bridged MnIII–FeIII compound, [NEt4][Mn(3,5-ClL)2(MeOH)]2Fe(CN)6], [3,5-ClLH2 = N,N′-bis(3,5-chlorosalicylidenato)-1,2-diamino propane)], 1, has been characterized by X-ray analyses, magnetic and photoluminescence measurements. The structure assumes a two-dimensional network consisting of Mn–NC–Fe–CN–Mn (Fe1–C19–N4 = 175.9(3)°, C19–N4–Mn1 = 145.5 (3)°). The magnetic properties of this compound indicate antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridges. Furthermore, solid state photoluminescence properties of complex 1 have been investigated at room temperature.
Graphical abstract2D trans-cyano-bridged MnIII–FeIII complex has been synthesized and characterized single crystal X-ray diffraction. The photoluminescence and magnetic properties of complex were also discussed.Figure optionsDownload full-size imageDownload as PowerPoint slide
