Article ID Journal Published Year Pages File Type
1308246 Inorganica Chimica Acta 2005 8 Pages PDF
Abstract
ReOCl3(L-L) and ReOCl2(OEt)(L-L) compounds were prepared by reaction of a diphosphine or diarsine with ReOCl3(OPPh3)(Me2S). They adopt the fac-trichloro and the trans-oxo-ethoxo structures, respectively. The UV-visible absorptions corresponding to the two lowest-energy spin-allowed HOMO-LUMO transitions are not greatly displaced compared to the related dppe compounds.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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