Coordination polymers of sulphur-donor ligands

This review gives an account of the coordination polymers that can be attained with ligands containing the sulphur-based dithiocarbamate (dtc), dithiocarboxylate and xanthate functional groups. The coordination modes adopted by the different sulphur-based ligands are discussed, and methods of attaining higher dimension complexes outlined. The review also addresses potential applications of such materials.

Graphical abstractThis review gives an account of the coordination polymers of ligands containing the sulphur-based dithiocarbamate (dtc), dithiocarboxylate and xanthate functional groups.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Review of coordination polymers of dithiocarbamate, dithiocarboxylate and xanthate ligands. ► A variety of coordination modes are observed. ► Polymers can be obtained through bridging sulfur ligands or bridging co-ligands.