Low-dimensional compounds containing cyano groups. XIX. Crystal structure, spectroscopic, thermal and magnetic properties of {[Cu(tn)2]3[Pt(CN)4]2}[Pt(CN)4] (tn = 1,3-diaminopropane) complex

Violet prismatic crystals of {[Cu(tn)2]3[Pt(CN)4]2}[Pt(CN)4] (tn = 1,3-diaminopropane) were crystallized from the water–methanol solution containing CuCl2·2H2O, tn and K2[Pt(CN)4]·3H2O. Prepared complex was characterized using elemental analysis, infrared and UV–Vis spectroscopy, magnetic measurement and thermal analysis. X-ray analysis revealed an ionic character of the complex containing mononuclear square planar [Pt(CN)4]2− complex anions and penta-nuclear [Cu(tn)2-Pt(CN)4-Cu(tn)2-Pt(CN)4-Cu(tn)2]2+ complex cations. The inner Cu(II) atom of the complex cation is hexa-coordinated, whereas two crystallographically equivalent peripheral Cu(II) atoms are penta-coordinated in the shape of a deformed square pyramid. Four v(CN) absorption bands observed in the IR spectrum are in agreement with the higher number of crystallographically different cyano groups and a broad highly asymmetric band observed in the reflectance UV–Vis spectrum is consistent with the presence of both hexa- and penta-coordinated Cu(II) atoms in the structure. The temperature dependence of the inverse susceptibility suggests the presence of a weak antiferromagnetic exchange coupling between Cu(II) ions. The complex is stable up to 210 °C when its two-stage thermal decomposition starts.

Graphical abstractIn this paper we present the synthesis, crystal structure, spectral, thermal and magnetic properties of new {[Cu(tn)2]3[Pt(CN)4]2}[Pt(CN)4] complex.Figure optionsDownload full-size imageDownload as PowerPoint slide