| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308440 | Inorganica Chimica Acta | 2013 | 8 Pages |
The reactivity of mixed complexes [PtCl2(L)(L′)] (L = MeCN, EtCN, CO), L′ = PPh3; L = η2-C2H4, CO; L′ = MeCN, EtCN) towards diethylamine has been investigated. The processes are chemo- (substitution versus addition) and stereo-selective in dependence of the stereochemistry of the precursor. The structures of [SP4-4]-[PtCl(CONEt2)(NHEt2)(PPh3)], [SP4-4]-1, trans-[PtCl2(NHEt2)(PPh3)], trans-2, and cis-[PtCl2{(E-)HNC(NEt2)Me}(PPh3)], cis-3a, are reported.
Graphical abstractThe reactivity of mixed complexes [PtCl2(L)(L′)] (L = MeCN, EtCN, CO), L′ = PPh3; L = η2-C2H4, CO; L′ = MeCN, EtCN) towards diethylamine has been investigated. The processes are chemo- (substitution versus addition) and stereo-selective in dependence of the stereochemistry of the precursor.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The reactivity of mixed complexes [PtCl2LL′] towards NHEt2 has been investigated. ► The processes are chemo- (substitution versus addition) and stereo-selective. ► The reaction outcome depends on the stereochemistry of the precursor.
