Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308504 | Inorganica Chimica Acta | 2009 | 9 Pages |
Abstract
Three new polymeric mercury(II) thiocyanate coordination polymers, {[Hg2(L4)(SCN)4]n (1), [Hg2(μ-L5)(μ-SCN)4]n[Hg2(μ-L5)(μ-SCN)4]2n (2) and [Hg(L6)(SCN)2]n (3); L4 = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene, L5 = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene and L6 = 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene) were prepared from reactions of mercury(II) thiocyanate with three organic nitrogen donor-based ligands under thermal gradient conditions using the branched tube method and fully characterized by infrared spectroscopy, elemental analysis, thermo gravimetric analysis, and single crystal X-ray diffraction.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ghodrat Mahmoudi, Ali Morsali,