Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308535 | Inorganica Chimica Acta | 2016 | 8 Pages |
Abstract
Cothermolysis of [(Ph)P(Se)(μ-Se)]2 or Woollins' reagent (WR) with Cp2Mo2(CO)4 (2) in toluene at 110 °C gave three metal cluster products as [Cp2Mo2{(μ-Se)2(PPh(Se))}{(μ-Se)(PPh)3] (3), Cp4Mo4(CO)3(μ-Se)4 (4) and a pair of polymorphic complexes of Cp3Mo3(CO)4[Se3(PPh)2] (5a and 5b) in moderate yields. However, a similar reaction at 70 °C gave only polymorphs 5a and 5b.91
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mei Lee Ooi, Richard C.S. Wong, Ward.T. Robinson,