Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308588 | Inorganica Chimica Acta | 2005 | 8 Pages |
Abstract
The reactions of quadruply bonded dimolybdenum complex, [Mo2(μ-OAc)4] (1), with Li[(NiPr)2CR] (R = tBu; 2a, Me; 2b, Ph; 2c), were investigated systematically. In the reaction of 1 with 2c, [Mo2(μ-OAc)2{μ-(NiPr)2CPh}2] (4) was formed accompanied by the formation of its stereoisomer 5. Complex 5 readily reacted with dry oxygen to give dinuclear Mo(V)-oxo complex, [{Mo(η-(NiPr)2CPh)oxo}2(μ-OAc)2(μ-oxo)] (6), which has a Mo-Mo single bond.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yoshitaka Yamaguchi, Sou Ozaki, Hideto Hinago, Kimiko Kobayashi, Takashi Ito,