| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308591 | Inorganica Chimica Acta | 2017 | 8 Pages |
Abstract
9-Methyladenium, 9-MeAH+, binds to cis-(NH3)2PtII via its N7 position to give 1:1 and 1:2 complexes, both of which have been isolated. The 1:2 complex is special in that it crystallizes with additional two equivalents of HNO3 per Pt, which are located in rectangular channels. pKa values of the 9-MeAH+ ligands have been determined.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+](/preview/png/1308591.png "First Page Preview: Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+")
Authors
Egla Yareth Bivián-Castro, Michael Roitzsch, Deepali Gupta, Bernhard Lippert,