Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308595 | Inorganica Chimica Acta | 2005 | 5 Pages |
Abstract
Reaction of Mo(CO)4(NCCH3)2 and 7-aza-2-tosylnorbornadiene (7-azaNBD) yielded five air-stable Mo complexes. One is Mo(CO)4(η4-7-azaNBD), in which the molybdenum atom is chelated by the two Ï-bond of 7-azaNBD. The other four are isomers of Mo(CO)2(η4-7-azaNBD)2, in which the molybdenum atoms are chelated by the nitrogen atom and one of the two double bonds of 7-azaNBD. All structures were fully characterized by NMR spectra. A single crystal of compound 4 was analyzed by X-ray diffraction analysis, which was found to be monoclinic with a = 8.4199, b = 23.984, c = 16.395 Ã
, and β = 99.99°.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mei-Fang Ding, Shaw-Tao Lin, Tashin J. Chow,