Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308756 | Inorganica Chimica Acta | 2009 | 4 Pages |
Abstract
Meso-tetraarylporphyrins (H2t(X)pp) and PCl5 leads to the formation of the intermediate sitting-atop complexes, [PCl3(H2t(X)pp)]Cl2, that two nitrogen atoms of pyrrolenine in the porphyrin core act as electron donors to a phosphorus(V) center and two pyrrolic protons remained still on the macrocycle.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hossein Dehghani, Maryam Shaterian,