Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1308762 | Inorganica Chimica Acta | 2009 | 9 Pages |
Abstract
Copper(I) thiosaccharinate in combination with triphenylphosphane and bis(diphenylphosphino)methane (dppm) produces a rich coordination chemistry. New uncommon mono-, di-, and tetra-nuclear complexes have been prepared and structurally characterized. Three different coordination forms of the thiosaccharinate anion are present in the new substances. The thioamidate acts as a two, four or six-electron donating ligand through its exocyclic S and endocyclic N atoms.
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Authors
Mariana Dennehy, Gabriela P. TellerÃa, Oscar V. Quinzani, Gustavo A. EcheverrÃa, Oscar E. Piro, Eduardo E. Castellano,