| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308827 | Inorganica Chimica Acta | 2009 | 8 Pages |
Abstract
Flexibility of acetate coordination is revealed for a series of preorganized dinickel(II) complexes, including distinct tilting and twisting of μ1,3-acetate bridges with respect to the bimetallic core. The strength of antiferromagnetic coupling is discussed in light of these structural variations, and tilting of the acetate C-C bond out of the pyrazolate-dinickel(II) plane is proposed to have a major effect.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Feng-Mei Nie, Guido Leibeling, Serhiy Demeshko, Sebastian Dechert, Franc Meyer,