| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1308999 | Inorganica Chimica Acta | 2008 | 6 Pages |
Abstract
The linkage isomers [Re(NCS)6]2â and [Re(NCS)5(SCN)]2â are formed by reaction of [ReBr6]2â with NCSâ in dimethylformamide. Some differences in the chemical behaviour allowed their separation and structural characterization in the form of (NBu4)2[Re(NCS)6] (1) and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] (2), respectively.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Linkage isomerism in the metal complex hexa(thiocyanato)rhenate(IV): Synthesis and crystal structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)]](/preview/png/1308999.png "First Page Preview: Linkage isomerism in the metal complex hexa(thiocyanato)rhenate(IV): Synthesis and crystal structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)]")
Authors
Ricardo González, Natalia Barboza, Raúl Chiozzone, Carlos Kremer, Donatella Armentano, Giovanni De Munno, Juan Faus,