Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)2(acac)](PF6) (2; bpyBr = 4-Bromo-2,2′-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)2(acac)](PF6) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2′-bipyridine) were prepared as candidates for building blocks. The 1H NMR, 13C NMR, UV–Vis, electrochemistry and FAB mass spectral data of these complexes are presented.

Graphical abstractTwo new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)2(acac)](PF6) (2; bpyBr = 4-Bromo-2,2′-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)2(acac)](PF6) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2′-bipyridine) were prepared as candidates for building blocks. The 1H NMR, 13C NMR, UV–Vis, electrochemistry and FAB mass spectral data of these complexes are presented.Figure optionsDownload full-size imageDownload as PowerPoint slide