Cobalt(III) complexes of some aromatic thiohydrazides – Synthesis, characterization and structure

[Co(NH3)5Cl]Cl2 forms neutral 1:3 complex by reaction with aromatic thiohydrazides, i.e. thiobenzhydrazide, o-hydroxythiobenzhydrazide, thiophen-2-thiohydrazide and furan-2-thiohydrazide. All these complexes are diamagnetic and have been characterized by elemental analysis and combination of spectroscopic methods. Cyclic voltammometry of the complexes shows irreversible metal centered and ligand centered electron transfer reactions. One complex, tris-o-hydroxythiobenzhydrazidocobalt(III), has been crystallized from DMSO solution to produce solvated crystals and its structure has been established by X-ray crystallography. Cobalt(III) ion is linked through three hydrazinic nitrogen and three sulfur atoms of three identical deprotonated ligand molecules in a distorted octahedral environment. Involvement of –OH group in intramolecular and intermolecular hydrogen bonding is crucial for crystal formation.

Graphical abstractCobalt(III) forms neutral 1:3 complexes with aromatic thiohydrazides. In these diamagnetic octahedral complexes cobalt(III) ion is linked through three hydrazinic nitrogen and three sulfur atoms of three identical deprotonated ligand molecules.Figure optionsDownload full-size imageDownload as PowerPoint slide