| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309203 | Inorganica Chimica Acta | 2010 | 10 Pages |
Abstract
A series of tetradentate copper macrocyclic complexes, which employ amine and thioether donor groups are reported. Apart from cis-[Cu(H4NbuSen)]+ all of the complexes are obtained in the copper(II) form. Crystallographic analysis shows that the copper(II) complexes all adopt a distorted planar geometry. In contrast, cis-[Cu(H4NbuSen)]+ adopts a distorted tetrahedral geometry. The complexes were subjected to electrochemical analysis and the effect of the solvent and the donor atoms positions on E1/2 discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Katherine D. Trotter, Michelle K. Taylor, John C. Forgie, John Reglinski, Leonard E.A. Berlouis, Alan R. Kennedy, Corinne M. Spickett, Rebecca J. Sowden,