| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309409 | Inorganica Chimica Acta | 2009 | 5 Pages |
Nanoparticles of a new PbII metal-organic polymer, [Pb(μ-pyr)(μ-I)2]n (1), with a net-like morphology have been synthesized by the reaction of pyrazine with Pb(NO3)2 and NaI via sonochemical irradiation. Nano-structured PbI2 and PbO were synthesized from compound 1 by calcination at argon and air atmospheres, respectively. The structure of 1 was determined by single crystal X-ray crystallography and the nano-structures were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The thermal stability of nano-sized and single crystalline samples of 1 were studied and compared.
Graphical abstractNanoparticles of a new PbII metal-organic polymer, [Pb(μ-pyr)(μ-I)2]n (1), with a net-like morphology have been synthesized by the reaction of pyrazine with Pb(NO3)2 and NaI via sonochemical irradiation. Nano-structured PbI2 and PbO were synthesized from compound 1 by calcination at argon and air atmospheres, respectively.Figure optionsDownload full-size imageDownload as PowerPoint slide
