| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309432 | Inorganica Chimica Acta | 2014 | 5 Pages |
•NHC-palladacycle/Cu cocatalyzed oxidation and Suzuki reactions.•Synthesis of biarylaldehydes from phenylboronic acids containing hydroxymethyl.•Three adducts of palladacycle 1–3 have been synthesized and characterized.
Three cyclopalladated 6-bromo-2-ferrocenylquinoline complexes with NHCs and PPh31–3 have been synthesized and characterized by elemental analysis, IR, NMR and single-crystal X-ray diffraction. Their application to Suzuki coupling of phenylboronic acid containing hydroxymethyl was also investigated. An efficient 3/Cu cocatalyzed oxidation/Suzuki coupling of aryl chlorides with phenylboronic acids containing hydroxymethyl in air has been developed.
Graphical abstractThree cyclopalladated 6-bromo-2-ferrocenylquinoline complexes with NHCs and PPh31–3 have been synthesized and characterized. An efficient 3/Cu cocatalyzed oxidation/Suzuki coupling of aryl chlorides with phenylboronic acids containing hydroxymethyl in air has been developed.Figure optionsDownload full-size imageDownload as PowerPoint slide
