| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309607 | Inorganica Chimica Acta | 2014 | 7 Pages |
Abstract
Geometrical distortions from iOh in tris(dithiocarbamato)bismuth(III) have been quantified by Continuous Shape Measure (CShM) analysis. BiS6 chromophore in [Bi(chmdtc)3] (1) is a distorted octahedron. The coordination geometry in [Bi(chedtc)3] (2) and [Bi(dchdtc)3] (3) should be described as distorted pentagonal pyramid. The higher BVS values observed in the present set of compounds support the fact that the Bi-S bonds are more covalent.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Subburayan Sivasekar, Kuppukkannu Ramalingam, Corrado Rizzoli, Nagarajan Alexander,