Syntheses, structures, thermal behavior and solution studies of two types of Hg(II) complexes with [1,3-di(2-methoxy)benzene]triazene

The reaction of [1,3-di(2-methoxy)benzene]triazene, [HL], with Hg(CH3COO)2 and Hg(SCN)2 in methanol as solvent, resulted in the formation of [HgL2] (1) and [HgL(SCN)] (2), respectively. These compounds were characterized by means of X-ray diffraction, FT-IR spectroscopy, CHN and TGA–DTA analysis. In the lattice of the compound 1, the mono-nuclear complexes were connected to dimer structure by intermolecular non-classical C–H···O hydrogen bonds. Also, weak Hg-η2-arene π-interactions link the dimers into 1D supramolecular chains. The compound 2 is a 2D coordination polymer induced by C–H···π stacking interactions between 1D chains produced by weak Hg-η3-η3-arene π-interactions. The results of studies of the stoichiometry and formation of complexes of 1 and 2 in methanol solution were found to be in support of their solid state stoichiometry.

Graphical abstractThe reaction of [1,3-di(2-methoxy)benzene]triazene, [L], with Hg(CH3COO)2 and Hg(SCN)2 in methanol as solvent, resulted in the formation of [HgL2] (1) and [HgL(SCN)] (2), respectively. In the lattice of the compound (1), a dimeric fragments through non classic C–H···O hydrogen bonds was present. In compound (2), chains consisting HgII ions were produced by Hg-η3-η3-arene π-interactions.Figure optionsDownload full-size imageDownload as PowerPoint slide