Article ID Journal Published Year Pages File Type
1309743 Inorganica Chimica Acta 2009 5 Pages PDF
Abstract

This paper reports the synthesis, characterisation and electrochemical properties of Fc-Pro-DCU 3. The activation of Fc-Pro-OH with DCC in the absence of racemization reducing agent results in the formation of N-(1-ferrocenoylpyrrolidine-2-carbonyl)-N,N′-dicyclohexylurea, as result of O/N-acyl shift in the acylisourea intermediate. Compound 3 exhibits quasi-reversible one-electron oxidation of ferrocenoyl moiety at E1/2 = 0.62 V.

Graphical abstractThe synthesis, characterisation and electrochemistry of the ferrocene proline urea conjugate Fc-Pro-DCU is reported.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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