| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309789 | Inorganica Chimica Acta | 2007 | 4 Pages |
Abstract
A tetrameric [Ag(μ-3,5-tBu2pz)]4 · CH2Cl2 (1 · CH2Cl2) has been prepared and structurally characterized. The four Ag-atoms are in an approximate rhombic arrangement with pyrazolato bridges alternating on either side of the Ag4-plane. A 1H NMR study shows partial decomposition of 1 to the mononuclear [Ag(3,5-tBu2pzH)2]+ in solution.
Graphical abstractA new structurally characterized tetranuclear Ag(I)-pyrazolate completes the series of Group-11, [M(μ-3,5-tBu2-pz)]4, complexes, M = Cu, Ag, Au.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Guang Yang, Raphael G. Raptis,